Size-Dependent Properties

© Northwestern University
(courtesy R.P. Van Duyne)
Size-dependent properties are the reason that nanoscale objects have the potential to significantly impact both science and industry.
Examples of size dependent properties include:
- Catalytic properties – how the material enhances chemical reactions
- Electrochemical properties – how the material transfers electrons to other chemical constituents
- Melting properties – how the material transitions from solid to liquid
- Magnetic properties – how the electrons interact to induce magnetic poles
- Optical properties – how the material interacts with light (e.g., its color)
It is difficult to predict at what size a particular material will transition from bulk to size-dependent properties. This threshold is different for each material and each property. For example, nanoscale gold will have different colors throughout the nanoscale size range, but the size-dependent catalytic properties do not dramatically change until gold features are smaller than five nanometers.

